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Transactions of the INDIAN CERAMIC SOCIETY   Vol. 84  2025
Influence of Metal Buffer Layer on Water Vapour Oxidation of Cr2AlC Coatings on Zry-4 Substrates for Accident Tolerant Fuel Applications
Yiming Lei,a Jinyu Shi,a, b Jie Zhanga, * and Jingyang Wanga
Pages : 1-7
DOI: 10.1080/0371750X.2025.2462819
Abstract
Cr2AlC, one of Al-containing MAX phases, was considered as an attractive coating candidate on Zry-4 alloys for accident tolerant fuel applications to enhance safety response under a loss of coolant accident. Cr, Nb and Mo were selected as the buffer layers between Cr2AlC coating and Zry-4 alloy, in order to extend the coating lifetime at elevated temperature (>900oC). The thermal compatibility of buffer layers in contact with Zry-4 alloy was investigated, and Cr was preferentially selected. Moreover, the feasibility of Cr coating as buffer layer between Zry-4 alloy and Cr2AlC coating was evaluated. Cr/Cr2AlC coating in high-temperature water vapour environment exhibited comparable oxidation resistance to the bulk Cr2AlC, and the parabolic rate constant decreased by two orders of magnitude compared to the zirconium alloy. [Keywords: Accident tolerant fuel, Cr2AlC coating, Buffer layer, High-temperature water vapour oxidation]
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