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Transactions of the INDIAN CERAMIC SOCIETY   Vol. 85  2026
Arsenic Doping Effects on the Structural and Electrical Properties of MoS2 Ceramics Designed for 5G/6G Technologies
Atef Fayez Qasrawi,a, c, * Nancy Asem Jaradata and Isam Alawnehb
Pages : 224-234
DOI:10.1080/0371750X.2026.2701655
Abstract
MoS2 ceramic powders were doped with arsenic (As) using a solid-state reaction technique, with As concentration varied from 0.0 to 6.68 at%. Increasing As content significantly enhanced crystallinity and reduced porosity from 61.7% to 23.2%, while transforming the grain morphology from lamellar and flaky to three- dimensional polygonal grains. Temperature-dependent electrical studies revealed a nearly four times increase in conductivity and the formation of shallower donor levels of 204 meV within the MoS2 band structure. Frequency-dependent dielectric analysis showed improved dielectric response and reduced loss tangent values from 0.111 to 0.049, achieving a ‘Qf0 ’ figure of merit of 20.33 GHz and a cutoff frequency of 25.89 GHz at maximum doping. Planar antennas fabricated from undoped and As-doped ceramics, tested between 0.1 and 6.0 GHz, exhibited resonant behaviour at 2.6-2.9 GHz with return loss exceeding –28 dB. These results demonstrate As-doped MoS2 ceramics as promising candidates for 5G/6G communications.
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